Bayes约束随机场下坝基溶蚀区随机模拟方法及其影响分析   总被引：1，自引：0，他引：1  

张社荣  王超  孙博 《岩土力学》2013,34(8):2337-2346

基于完全随机场模拟溶蚀岩体可能会高估其空间变异性和不能有效地利用溶蚀以外的地质信息和实践经验,提出用Bayes约束参数随机场模型描述坝基溶蚀区的随机模拟方法。引入Bayes公式,对溶蚀区域岩土参数的统计特性进行修正,反映出地质勘测的新增地质信息和试验参数信息,建立约束随机场,并在此基础上进行随机有限元分析,研究坝基溶蚀对大坝结构性态的作用效应。计算结果表明,相对于完全随机场模型,Bayes约束随机场模型更为客观地考虑了溶蚀岩体的空间变异性,有效地降低了溶蚀参数完全随机场下结构响应的模拟方差。在概率分析过程中,推荐蒙特卡洛响应面耦合方法（MC-RSM）作为适用于复杂工程的随机模拟方法,该方法能够代替直接MC法对同样力学机制的不断重复,减小计算时间成本。  相似文献   

Fatty acid profiles of benthic environment associated with artificial reefs in subtropical Hong Kong     

Siu Gin Cheung  Paul K.S. Shin 《Marine pollution bulletin》2010,60(2):303-308

Artificial reefs can enhance habitat heterogeneity, especially in seabed degraded by bottom-dredging and trawling. However, the trophodynamics of such reef systems are not well understood. This study provided baseline data on trophic relationships in the benthic environment associated with artificial reefs in late spring and mid summer of subtropical Hong Kong, using fatty acid profiles as an indicator. Data from sediments collected at the reef base, materials from sediment traps deployed on top and bottom of the reefs, total particulate matter from the water column and oyster tissues from reef surface were subjected to principal component analysis. Results showed variations of fatty acid profiles in the total particulate matter, upper sediment trap and oyster tissue samples collected in the two samplings, indicating seasonal, trophodynamic changes within the reef system. The wastes produced by fish aggregating at the reefs can also contribute a source of biodeposits to the nearby benthic environment.  相似文献   

Origin of CO_2 in natural gas from the Triassic Feixianguan Formation of Northeast Sichuan Basin     

HUANG SiJing  HUANG KeKe  TONG HongPeng  LIU LiHong  SUN Wei & ZHONG QianQian State Key Lab of Oil  Gas Reservoir Geology  Exploitation 《中国科学:地球科学(英文版)》2010,(5)

The natural gas from the Triassic Feixianguan Formation of Northeast Sichuan Basin contains high H2S whereas relatively low CO2 concentrations and the CO2 display high δ13C values (ranging from -5.81‰ to 3.3‰ (PDB)). This seems to contradict the conventional wisdom that TSR should be a primary source of CO2 in natural gas from the Feixianguan Formation. In contrast, many authigenic calcite samples from these sites display very low δ13C values (ranging from -18.4‰ to -10.3‰ (PDB)). This suggests that the carbon from TSR source dominated the formation of calcite whereas the carbon from inorganic source came into CO2 in natural gas. In order to assess the origin of CO2 from these H2S-rich sites, we have calculated the relative contributions of organic and inorganic carbon sources to the CO2 and authigenic calcite. The organic carbon source possibly originated from TSR, whereas the inorganic one might be generated from marine carbonates dissolution. This calculation is based on the carbon isotopic compositions of CO2 and authigenic calcite as well as an isotopic mass balance. The results show that the contribution of organic carbon source to the CO2 is only 2%, whereas that to authigenic calcite is as high as 43% on average. Such results combined with thermodynamic evidence indicate that the isotopically light CO2 produced by TSR process may contribute to authigenic calcite precipitation during burial diagenesis. Distinguishable from Ordovician reservoir of Tarim Basin, Feixianguan reservoir of Northeast Sichuan Basin experienced rapid tectonic uplift due to Yanshanian movement after TSR occurred. Such tectonic event could induce temperature decrease and further promote carbonates dissolution. During these processes, secondary porosity has developed in Feixianguan carbonate reservoirs. Therefore, much attention should be paid to the structural highs in search of high quality carbonate reservoirs.  相似文献   

Determination of Cyanuric Acid in Swimming Pool Water and Milk by Differential Pulse Polarography     

Ümmihan T. Yilmaz  Zehra Yazar 《洁净——土壤、空气、水》2010,38(9):816-821

Cyanuric acid is a suspected gastrointestinal or liver toxicant in humans. Therefore, determination of trace cyanuric acid is very important, in this work a novel, sensitive, and reliable method was developed using differential pulse polarography. Optimum conditions for analytical determination were found to be at a pH of 9.5, Britton–Robinson at a reduction potential of ?105 mV. Experimental results indicate an excellent linear correlation between the peak current and the concentration in the range of cyanuric acid from 0.5 to 27.0 µM (0.06–3.5 µg mL^?1) with a correlation coefficient of 0.997. The limit of detection and limit of quantification were obtained as 0.15 and 0.5 µM (0.02–0.06 µg mL^?1), respectively. The proposed method was successfully applied to the determination of cyanuric acid in pool water and in spiked milk. Cyanuric acid level in swimming pool water was found as 2.54 ± 0.47 µg mL^?1 (19.7 ± 2.29 µM) in swimming pool water for N = 4 and 95% confidence interval. The recoveries were found to be sufficient. Also, the standard deviation of the data was low which shows high accuracy and precision of proposed differential pulse polarographic method. The influences of some other commonly found inorganic salts on the determination of cyanuric acid were also examined. Some interfering species were eliminated using complexing agents, e.g., EDTA.  相似文献   

High urine hippuric acid level among police working close to traffic in an urban area,Thailand: a preliminary study     

Viroj Wiwanitkit  Jamsai Suwansaksri  Suphan Soogarun 《Stochastic Environmental Research and Risk Assessment (SERRA)》2008,22(2):281-283

Toluene is of particular concern because recent research indicating that toluene exposure can result in several toxicities. Hence, toluene exposure is of particular concern because of ongoing exposure to thousands of workers in the industrial plants. Determination of the urine hippuric acid level is accepted as a helpful for monitoring risk groups of workers. Apart from the industrial workers, there are other occupations with high risk for toluene exposure. In this study, we study another at-risk occupation, the police. In this study, 45 urine samples were obtained from 45 Thai police working close to traffic in an urban area for determination for urine hippuric acid level. The average urine hippuric acid level was 0.70 ± 0.70 mg/gCr, respectively. This average is significant higher than that of the control non-exposed Thais (P < 0.05). Working in the air pollution in the urban area can be health hazard for the police. Exposure to the toluene from automobile exhaust can be an important occupational problem for these police.  相似文献   

Production of Levulinic Acid from Bagasse and Paddy Straw by Liquefaction in the Presence of Hydrochloride Acid     

Lifeng Yan  Naikun Yang  Hao Pang  Bing Liao 《洁净——土壤、空气、水》2008,36(2):158-163

A method of levulinic acid production from bagasse and paddy straw is presented. Biomass waste was mixed with hydrochloride acid and water, and then liquefied at about 200°C in a pressurized reactor. Both the mass of the biomass and the amount of hydrochloride acid were kept as constants, and the effects of temperature, reaction time, and acid concentration on the levulinic acid yield were studied. It was found that the yield of levulinic acid was maximum when the reaction temperature was carried out for 45 min at 220°C using 4.45% concentration of hydrochloride acid, and the maximum yields of levulinic acid were 22.8 and 23.7% for bagasse and paddy straw, respectively. The products were analyzed using NMR, HPLC, and GC/MS.  相似文献   

Differential developmental toxicity of naphthoic acid isomers in medaka (Oryzias latipes) embryos   总被引：1，自引：0，他引：1  

Michael W. Carney  Kyle Erwin  Ron Hardman  Bonny Yuen  David C. Volz  David E. Hinton  Seth W. Kullman   《Marine pollution bulletin》2008,57(6-12):255

Polycyclic aromatic hydrocarbons (PAHs) are widespread persistent pollutants that readily undergo biotic and abiotic conversion to numerous transformation products in rivers, lakes and estuarine sediments. Here we characterize the developmental toxicity of four PAH transformation products each structural isomers of hydroxynaphthoic acid: 1H2NA, 2H1NA, 2H3NA, and 6H2NA. Medaka fish (Oryzias latipes) embryos and eleutheroembryos were used to determine toxicity. A 96-well micro-plate format was used to establish a robust, statistically significant platform for assessment of early life stages. Individual naphthoic acid isomers demonstrated a rank order of toxicity with 1H2NA > 2H1NA > 2H3NA > 6H2NA being more toxic. Abnormalities of circulatory system were most pronounced including pericardial edema and tube heart. To determine if HNA isomers were AhR ligands, spatial-temporal expression and activity of CYP1A was measured via in vivo EROD assessments. qPCR measurement of CYP1A induction proved different between isomers dosed at respective concentrations affecting 50% of exposed individuals (EC50s). In vitro, all ANH isomers transactivated mouse AhR using a medaka CYP1A promoter specific reporter assay. Circulatory abnormalities followed P450 induction and response was consistent with PAH toxicity. A 96-well micro-plates proved suitable as exposure chambers and provided statistically sound evaluations as well as efficient toxicity screens. Our results demonstrate the use of medaka embryos for toxicity analysis thereby achieving REACH objectives for the reduction of adult animal testing in toxicity evaluations.  相似文献   

The volcanic acidification of glacial Lake Caviahue,Province of Neuquen,Argentina     

Johan C. Varekamp 《Journal of Volcanology and Geothermal Research》2008

Lake Caviahue (northern Patagonia, Argentina) is a large glacial lake acidified by volcanic fluids from Copahue volcano. The lake and the feeding rivers were sampled annually from 1997 till early 2006, including the eruptive period of 2000. Lake Caviahue waters evolved over time, with the most concentrated waters in 2000 during the eruptive period, followed by gradual dilution that was interrupted by renewed acidification in 2003–2004. Inversion of the lake water data and application of a dynamic non-steady state model for the lake provides our best quantitative estimates for the variation in element fluxes over the 9-year period. The model flux results agree well with most of the measured fluxes. The Copahue hydrothermal system had gently declining element fluxes between 1997 and mid-1999, although the lake was still becoming more concentrated. About 2–3 months before the 2000 eruption, element fluxes increased strongly, but the hydrothermal fluxes almost shutoff directly after the main eruptive events. The fluxes of several elements recovered post-2001, with an increase in element fluxes in 2003–2004; the lake became more dilute between 2004 and 2006. The intrusion of new magma into the hydrothermal system just prior to the 2000 eruption led to enhanced water rock interaction, with higher concentrations of the rock forming elements in the fluids, and the hot spring flow rate increased as a result of the higher pressure in the reservoir. The fluids became saturated in alunite and jarosite, and they were already saturated with anhydrite. Precipitation of these minerals possibly led to a decreased permeability of the hydrothermal reservoir, leading to the strongly reduced element fluxes just after the eruption. In addition, K, Al and S were retained in the newly precipitated minerals as well, further diminishing their export. The acidification in 2003–2004 may have resulted from a new small intrusion of magma or resulted from seismic activity that created new permeability and fresh rock surfaces for water rock interaction. The volcano is a significant source of toxic trace elements such as F, As, B and Li as well as a nutrient (P) for the local watershed. Monitoring of the hydrothermal fluids in the river that drains Copahue, especially the S/Cl, Mg/Cl and Mg/K values as well as the magnitude of the element fluxes would provide the best information for eruption forecasting for this volcano.  相似文献   

环境因子对2种南极绿藻脂肪含量和脂肪酸组成的影响   总被引：3，自引：1，他引：2  

缪锦来  王波  阚光锋  丁燏  姜英辉  侯旭光  李光友 《海洋科学》2005,29(1):4-11

通过气相色谱方法对南极冰藻的脂肪酸进行了分析,发现环境因素对2种绿藻总脂含量有一定的影响：(1)温度对Pymmixtomonas sp,总脂含量影响不大,一般为8．3％～8．9％,Chlorophyceae L-4在2℃时的总脂含量最高为10.33％;(2)光强显著地影响这2种绿藻脂肪在细胞内的积累。随着光强由限制生长的39 lx增加到3900 lx,2种绿藻的脂肪酸含量降低：(3)盐度的提高有利于2种绿藻脂肪的积累;(4)营养盐的限制也利于2种绿藻脂肪的积累。在氮源缺乏条件下,Pyramidomonas sp,和Chlorophyceae L-4细胞内脂肪大量积累,含量分别是以NH4Cl为氮源的2．2和3.2倍。环境因素对2种绿藻脂肪酸组成和含量的影响不同,其脂肪含量的改变反映了南极冰藻生长的改变。环境因子能够影响这2种绿藻的脂肪含量,同样也影响到它们的生长。在适合南极冰藻生长的条件下,脂肪酸积累降低;反之,在南极冰藻生长受到限制的条件下,脂肪合成增加。这表明2种绿藻的脂肪含量随生存环境的变化而变化。环境因子同样影响到2种绿藻的脂肪酸组成,尤其是不饱和脂肪酸的组成和含量,但组成和其生长不存在相关性。环境因子(温度、光强、盐度和营养盐)对2种绿藻脂肪酸的测定结果表明,在2种绿藻中,多不饱和脂肪酸的含量高于单不饱和脂肪酸和饱和脂肪酸。因此。这2种绿藻可望为多不饱和脂肪酸的开发利用提供藻种资源。  相似文献   

Sulfuric acid as an agent of carbonate weathering constrained by δC_DIC: Examples from Southwest China     

Si-Liang Li  Damien Calmels  Guilin Han  Jrme Gaillardet  Cong-Qiang Liu 《Earth and Planetary Science Letters》2008,270(3-4):189-199

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